Safety

THE CHEMISTRY LABORATORY

The risks prevention, their definition and resolution connected with the activities of laboratories is very delicate.

The laboratory must have in terms of structure all measures required by regulations.

In the universities, both in teaching and in research activities, the objectives of security are sometimes identical, but in both cases it is required to the staff a great attention and the ability to detect danger in the diversity of operations.

 

ACTIVITIES AND RISKS CLASSIFICATION IN THE CHEMICAL LABORATORIES 

These activities are a series of related risks arising from the various operations that are carried out, to jeopardize the health of operators; risks that can be either type Accident (mainly related to risk of traumatic physical injury) and environmental hygiene type (associated with exposure to agents and / or potentially harmful factors present in the workplace laboratories).



GENERAL RISKS IN CHEMICAL LABORATORIES

 

The most frequentaccidents in chemistry laboratories are:

- Risk of injury for cutting wounds - Risk of injury from thermic burns.
- Risks of injuries related to the use of equipment under pressure.
- Risk of injury from electrocution.
- Risk of injury due to the handling of chemicals.


Among the environmental hygiene risks are highlighted:

Risks due to physical agents (noise, vibration, microclimate, microwave).
Risks due to chemical agents (inhaled smoke, fog, dust, contact, ingestion of chemicals and / or biological "harmful") substances.

 

CHEMICALS 

Definitions


Substances - The chemical elements and their compounds in their natural state or produced by industry, possibly containing additives necessary for them to the market.

Preparations - mixtures or solutions composed of two or more substances.

Labelling - All indications appear on a special label or directly on the printing or engraving or relief.

 

The label

The label assumes an important role in giving us a lot of information (synthetic) on the chemical and physical characteristics of the substance and / or preparation. It also provides the first signs regarding potential risks of substance and / or product.
More specifically: the label takes account of all the potential risks associated with the normal handling and use of the substances in the manner in which they are marketed;

The tag must provide the following information:

- The name of the chemical substance.
- The name and headquarters of the manufacturer.
- The symbols of danger (T, X, Xi, XN, C, E, F, and O) and its pictograms.
- The risk phrases (R-phrases), safety advice (S phrases).


Proceeding researching on the dangers of substances additional symbols are used to refine the dangers while maintaining the same pictograms:

(F+) extremely flammable,
(T+) very toxic,
(N)  dangerous for the environment

Similarly other substances have been defined that involve more specific risks such as toxic for reproduction (harmful to the normal development of the fetus) and mutagenic (harmful to the development of normal cells).


Risk phrases on the label (some examples)

Dangerous substances to humans:

R 40 possibility of irreversible effects
R 45 may cause cancer
R 46 may cause heritable genetic damage
R 47 can cause congenital malformations


Dangerous substances to the environment:

R 50 highly toxic to aquatic organisms
R 51 toxic to aquatic organisms
R 52 harmful to aquatic organisms
R 53 may cause long-term adverse effects in the aquatic environment
R 54  toxic to plants
R 55 toxic to wildlife
R 56 toxic to soil organisms
R 57 toxic to bees
R 58 may cause long-term adverse effects on the environment
R 59 dangerous for the ozone layer

Recommendations of prudence in the label

Although these phrases are classified as recommendations must not think that their importance is minor; follow these recommendations is required.
The safety advice along with rules of conduct, are the basis of risk prevention and decrease the likelihood that they will occur.

As mentioned earlier, they are marked with the letter S which normally live in the risk phrases

S 1 store locked up
S 2 store in a cool place
S 15 conserve heat
S 22 not breathe dust
S 24 avoid contact with skin
S 25 avoid contact with eyes


See Regulations on 'Labelling of dangerous substances" 
See Regulations on the "Classification of carcinogenic, mutagenic and toxic substances for reproduction "

 

STANDARDS OF CONDUCT 

The lack of information and carelessness are the main causes of accidents that occur in chemistry laboratories.
It is appropriate to draw attention to the importance of this issue expressly provided for in Decree-Law 
626/94.

 

Right Teacher

The right is the freedom to choose the type of exercise that it intends to make and to have a structure for the implementation of its activities laboratory, it should be remembered that the teacher should also assess the feasibility of the exercise in advance and, if the difficulties are difficult to be solved, be available to substitute the type of exercise.  


Duty Teacher 

The explicit duty of the teacher is to give students information on the operations taking place in the laboratory and the specific rules relating to security exercises that will take place and the risks related to them.

Student Rights 

He has the right to be informed on the risks and safety standards and intrinsic behavior of the laboratory. Furthermore, it must be made aware of the equipment and individual protection measures enabled in the laboratories.  


Duties Student

The student has a duty to inform themselves about the risks and the obligation to meet safety standards and provided all norms of behavior.



MAJOR RULES OF CONDUCT TO BE MET IN THE CHEMICAL LABORATORIES

 Before using any chemical product must acquire information about its characteristics through security ballot: risk phrases, safety advice. Follow the directions given to the handling, storage and disposal.

• To reduce the risk of initiation, development of fire and explosion, to eliminate the risk of exposure to hazardous substances, chemical reactions with the development of dangerous gases or vapours, chromatography "in the column" using organic solvents, the use equipment that can release into the smoke, gases or vapours (eg rotavapor retrieval system without solvents), or racking levy solvents, especially birds, for quantities strictly necessary for the performance of laboratory activities must be made exclusively inside the chemistry hood (confinement in a delimited and adequately ventilated). For use in safety hood, please refer to paragraph 2.

•  Do not place in the laboratory substances and objects to work. (For example coats, duvets, backpacks, etc.).

• Do not leave not identifiable material in the laboratory and in the hood.


• All containers must be properly labelled so you can recognize anytime content.


• Do not leave without control chemical reactions or apparatus in operation and, where appropriate, ensure the effectiveness of security systems.


• In laboratory is forbidden to eat, drink and smoke.


• In laboratory must always be worn the shirts.


• The laboratory must be kept clean and tidy.


• Do not ever work alone, especially outside official working.


• At the end of the activities promptly remove from the work plans glassware and equipment used.


• Collect, separate and delete properly chemical waste, solid and liquid produced in the laboratory, it is forbidden to download or abandon them in the sewer.


• Avoid over-crowding in the laboratories.


• Report to the responsible laboratory accident or unsafe conditions.


•The head of the laboratory must properly instruct the staff is concerned with his own laboratory, including students, trainees, fellows and Ph.D. students, in relation to the activities that they must perform, so that all are informed about:
possible risks in the workplace and risks arising from the performance of different tasks;
possible damage resulting from the use of dangerous substances, including gases and / or dangerous equipment;
measures of prevention and protection to be implemented in each specific situation.


• The head of the laboratory must establish a CPS identifying the actual or potential risks for each stage of processing and showing behaviour which must be undertaken to eliminate or minimize these risks.


• The head of the laboratory must ensure the proper application of the measures of prevention and protection by all those who frequent the laboratory, with particular attention to the students.


• First of all must be adopted collective security means (for example, business at risk just inside the hood, tapping the source, ventilation, etc..).  When the collective means of protection not be able to eliminate the risk of exposure to hazardous substances, it is also necessary to use the devices Personal Protective Equipment (PPE) appropriate for each type of activity and for each level of risk (for example, to gloves lose, goggles, masks protective footwear). The PPE should be used properly and kept in a good state of repair.


• Where possible, we must adopt methods that can reduce the presence of dangerous concentrations of flammable substances and chemically unstable.
 
• Avoid the presence of sources of ignition that could lead to fires and explosions (for example, you are prohibited from using bunsen burners or any other free flame, in the presence of flammable substances and outside the chemical hood).


• The electrically powered equipment used in laboratories, both inside and outside the chemistry hood, must have a "safe electrical system," that is, with special protections, designed and installed in relation to the types of substances used in operating procedures.  Fundamental requirement of the plant, should be to reduce the risk of ignition, both during normal operation, both because of a malfunction.
In the case of ordinary operation, the causes of ignition can be, for example: the electric arc product during opening and closing of a switch; achieve surface temperatures dangerous for Joule effect.  In case of failure (for example, following a short circuit) can unleash sparks, can form an electrical arc or you can determine up-temperature, with enough power to trigger an explosive atmosphere.


• The equipment should ensure the control of the operating conditions
.
 

 

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